A Zwitterionic Phosphonium Stannate(II) via Hydrogen Splitting by a Sn/P Frustrated Lewis‐Pair and Reductive Elimination
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چکیده
منابع مشابه
Phosphonium Formation by Facile Carbon-Phosphorus Reductive Elimination from Gold(III).
A recent trend in homogeneous gold catalysis has been the development of oxidative transformations relying on Au(I)/Au(III) redox cycling. Typically, phosphine-supported Au(I) precatalysts are used in the presence of strong oxidants to presumably generate phosphine Au(III) intermediates. Herein, we disclose that such Au(III) complexes can undergo facile C(aryl)-P reductive elimination to afford...
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In analogy to transition metal complexes, coordination compounds of the main group metals can be also classified according to the electron configuration at the metal. Generally, the main group metals occur in oxidation states with so, s2, s2p2 and s2p4 ground states. Recently, we studied the photolysis of so and s2 systems [l-4]. We now report the first results on the photochemistry of an s2p2 ...
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ژورنال
عنوان ژورنال: Chemistry – A European Journal
سال: 2020
ISSN: 0947-6539,1521-3765
DOI: 10.1002/chem.202004425